$pH$ of a mixture of $1 \ M \ HA$ $(pK_a = 4.2)$ and $1 \ M \ NaA$ is $4.5$. In $300 \ mL$ of buffer,the volume of $HA$ is $....... \ mL$ $[\log \ 2 = 0.3]$

Which of the following mixtures will form a buffer solution?

Which of the following solutions can act as a buffer?

$A$ buffer solution of $100 \ mL$ has a $pH$ value of $4$. When $1 \ mL$ of dilute $HCl$ is added to it,what happens to the $pH$ of the buffer solution?

In an acidic buffer,$0.25 \ M$ $CH_3COOH$ is added to $0.125 \ M$ $NaCH_3COO$ solution. Calculate the $pH$ of the buffer. Given $K_a$ of $CH_3COOH = 1.8 \times 10^{-5}$. [Formula: $pH = pK_a + \log \frac{[Salt]}{[Acid]}$]

One litre buffer solution was prepared by adding $0.10 \ mol$ each of $NH_3$ and $NH_4Cl$ in deionised water. The change in $pH$ on addition of $0.05 \ mol$ of $HCl$ to the above solution is $............ \times 10^{-2}$ ($Nearest$ $integer$) ($Given$: $pK_b$ of $NH_3 = 4.745$ and $\log_{10} 3 = 0.477$)