Identify the correct reactions and observations from the following:
$(1) \ NH_4^+ \xrightarrow[K_2HgI_4]{KOH} \text{ Brown ppt. (Nessler's reagent)}$
$(2) \ Ni^{2+} \xrightarrow{dmg/OH^-} \text{ Rosy red ppt.}$
$(3) \ FeCl_3(aq.) \xrightarrow{NH_4OH} \text{ Reddish brown ppt.}$
$(4) \ CuSO_4(aq.) \xrightarrow{\text{excess } NH_4OH} \text{ Deep blue solution}$

Of the following sulphides,which one is insoluble in dilute acids but soluble in alkalies?

Sometimes yellow turbidity appears on passing $H_2S$ gas even in the absence of the second group radicals. This happens because

Choose the correct tests with respective observations.
$(A)$ $CuSO_4$ (acidified with acetic acid) $+$ $K_4[Fe(CN)_6]$ $\rightarrow$ Chocolate brown precipitate.
$(B)$ $FeCl_3 + K_4[Fe(CN)_6]$ $\rightarrow$ Prussian blue precipitate.
$(C)$ $ZnCl_2 + K_4[Fe(CN)_6]$,neutralised with $NH_4OH$ $\rightarrow$ White or bluish white precipitate.
$(D)$ $MgCl_2 + K_4[Fe(CN)_6]$ $\rightarrow$ Blue precipitate.
$(E)$ $BaCl_2 + K_4[Fe(CN)_6]$,neutralised with $NaOH$ $\rightarrow$ White precipitate.
Choose the correct answer from the options given below:

$A$ solution of a metal ion,when treated with $KI$,gives a red precipitate which dissolves in excess $KI$ to give a colourless solution. Moreover,the solution of the metal ion,on treatment with a solution of cobalt$(II)$ thiocyanate,gives rise to a deep blue crystalline precipitate. The metal ion is:

Which ion is not precipitated by both $HCl$ and $H_2S$?