$CH_3COOH_{(l)} + C_2H_5OH_{(l)} \rightleftharpoons CH_3COOC_2H_{5_{(l)}} + H_2O_{(l)}$. In the above reaction,one mole of each of acetic acid and alcohol are heated in the presence of a little conc. $H_2SO_4$. On equilibrium being attained:

For the reaction $Br_2 \rightleftharpoons 2Br$,the equilibrium constants at $327\,^oC$ and $527\,^oC$ are $6.1 \times 10^{-12}$ and $1.0 \times 10^{-7}$ respectively. The reaction is ...........

The surface of copper gets tarnished by the formation of copper oxide. $N_2$ gas was passed to prevent the oxide formation during heating of copper at $1250 \ K$. However,the $N_2$ gas contains $1 \ \text{mole}\%$ of water vapour as impurity. The water vapour oxidises copper as per the reaction given below:
$2 Cu_{(s)} + H_2O_{(g)} \longrightarrow Cu_2O_{(s)} + H_{2(g)}$
$p_{H_2}$ is the minimum partial pressure of $H_2$ (in $\text{bar}$) needed to prevent the oxidation at $1250 \ K$. The value of $\ln(p_{H_2})$ is . . . . .
(Given: total pressure $= 1 \ \text{bar}$,$R = 8 \ J \ K^{-1} \ mol^{-1}$,$\ln(10) = 2.3$. $Cu_{(s)}$ and $Cu_2O_{(s)}$ are mutually immiscible.
At $1250 \ K$: $2 Cu_{(s)} + 1/2 O_{2(g)} \longrightarrow Cu_2O_{(s)}; \Delta G^\theta = -78,000 \ J \ mol^{-1}$
$H_{2(g)} + 1/2 O_{2(g)} \longrightarrow H_2O_{(g)}; \Delta G^\theta = -1,78,000 \ J \ mol^{-1}$)

$37.8 \ g$ $N_2O_5$ was taken in a $1 \ L$ reaction vessel and allowed to undergo the following reaction at $500 \ K$:
$2N_2O_{5(g)} \rightarrow 2N_2O_{4(g)} + O_{2(g)}$
The total pressure at equilibrium was found to be $18.65 \ bar$. Then,$K_p = \text{ . . . . . . } \times 10^{-2}$ [nearest integer].
Assume $N_2O_5$ to behave ideally under these conditions.
Given: $R = 0.082 \ bar \ L \ mol^{-1} \ K^{-1}$

Match the items in List-$X$ with List-$Y$ and select the correct option.

List-$X$	List-$Y$
$(A)$ $A_{(g)} \rightleftharpoons B_{(g)} + \text{Heat}$	$(i)$ Equilibrium constant
$(B)$ $r_b/r_f$	$(ii)$ Favored at low temperature
$(C)$ $r_f/r_b$	$(iii)$ [Equilibrium constant]$^{-1}$
$(D)$ $2A_{(g)} + B_{(g)} \rightleftharpoons C_{(g)}$	$(iv)$ $A_{(g)} + B_{(g)} \rightleftharpoons C_{(g)} + D_{(g)}$
$(E)$ Effect of pressure	$(V)$ $\Delta n < 0$

For the reaction,$2SO_{2(g)} + O_{2(g)} \to 2SO_{3(g)}$
$\Delta H = -57.2 \ kJ \ mol^{-1}$ and $K_C = 1.7 \times 10^{16}$
Which of the following statement is $INCORRECT$?