$NH_3 + O_2 \xrightarrow[500 \ K]{Pt} W + H_2O$
$W + O_2 \rightleftharpoons X$
$X + H_2O \rightleftharpoons Y + W$
Which of the following statements is correct?

  • A
    $W$ is used as an anaesthetic.
  • B
    Conc. $Y + Cu \to NO_{(g)}$
  • C
    Dil. $Y + Zn \to N_2O_{(g)}$
  • D
    Conc. $Y + I_2 \to HIO_4$

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Given below are two statements: one is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$.
Assertion $(A)$ : $PH_3$ has lower boiling point than $NH_3$.
Reason $(R)$ : In liquid state $NH_3$ molecules are associated through van der Waals forces,but $PH_3$ molecules are associated through hydrogen bonding.
In the light of the above statements,choose the most appropriate answer from the options given below:

Which nitrogen trihalide is the least basic?

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