For the reaction $Cl_{(g)} + e^- \to Cl^-_{(g)}$,the value of $\Delta H$ is ...........

  • A
    Positive
  • B
    Negative
  • C
    Zero
  • D
    None of these

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Within each pair of elements of $F$ and $Cl$,$S$ and $Se$,and $Li$ and $Na$,respectively,the elements that release more energy upon an electron gain are

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What is the correct order of electron affinity for the elements of the oxygen group in the periodic table?

The formation of the oxide ion,$O^{2-}_{(g)}$,from oxygen atom requires first an exothermic and then an endothermic step as shown below:
$O_{(g)} + e^- \to O^{-}_{(g)} ; \Delta_f H^{\Theta} = -141 \ kJ \ mol^{-1}$
$O^{-}_{(g)} + e^- \to O^{2-}_{(g)} ; \Delta_f H^{\Theta} = +780 \ kJ \ mol^{-1}$
Thus,the process of formation of $O^{2-}$ in gas phase is unfavourable even though $O^{2-}$ is isoelectronic with neon. It is due to the fact that,

Among the following configurations,the element which has the highest electron affinity is

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