Which of the following orders is incorrect?

What is meant by diagonal relationship?

Which of the following statements are correct?
$(i)$ First ionisation enthalpy of $He < $ Second ionisation enthalpy of $Li$.
$(ii)$ $Li$ has the highest second ionisation enthalpy.
$(iii)$ All $d$-block elements are transition elements.
$(iv)$ The only alphabet not found in the periodic table is the letter '$J$'.
$(v)$ Francium concentration is $\sim 10^{-18} \ ppm$ on Earth.

State whether the following statements are true or false:
$(i)$ As the atomic number increases in a period,the nuclear charge increases,therefore the ionization enthalpy increases.
$(ii)$ As the metallic character of elements increases,the atomic radius generally increases.
$(iii)$ $Mn$ $(Z = 25)$ is a transition element. Although it is a $3d$-orbital element,its position in the periodic table is in the $4^{th}$ period.

Describe the periodicity of the first ionization enthalpy for elements with atomic numbers $1$ to $60$.

The first ionization energy for $Li$ is $5.4 \ eV$ and electron affinity of $Cl$ is $3.61 \ eV$. The $\Delta H$ (in $kJ/mol$) for the reaction $Li_{(g)} + Cl_{(g)} \to Li^{+}_{(g)} + Cl^{-}_{(g)}$ is (if resulting ions do not combine with each other) ($1 \ eV = 1.6 \times 10^{-19} \ J$,$N_A = 6.022 \times 10^{23} \ mol^{-1}$)