$36 \, mL$ of pure water takes $100 \, sec$ to evaporate from a vessel and heater connected to an electric source which delivers $806 \, watt$. The $\Delta H_{\text{vaporization}}$ of $H_2O$ is $... \, kJ/mol$

The heat of vaporisation and heat of fusion of $H_2O$ are $540 \, cal/g$ and $80 \, cal/g$. The ratio of $\frac{\Delta S_{vap}}{\Delta S_{fusion}}$ for water is :-

At $300 \ K$, $3.0 \ \text{moles}$ of an ideal gas at $3.0 \ \text{atm}$ pressure is compressed isothermally to one half of its volume by an external pressure of $6.0 \ \text{atm}$. The work done (in $kJ$) is. Given, $R=0.082 \ \text{L atm K}^{-1} \text{mol}^{-1}$ $(1 \ \text{L atm} = 101.3 \ \text{J})$.

Fill in the blanks given below:
$(i)$ The law of thermodynamics is actually the law of ......... .
$(ii)$ $A$ thermometer measures temperature according to the ......... law of thermodynamics.
$(iii)$ The foundation of thermochemistry is based on the ......... law of thermodynamics.
$(iv)$ The amount of heat required to raise the temperature of a substance by $1^{\circ}C$ is called the ......... of that substance.

Standard entropies for $H_2, Cl_2$ and $HCl$ are $60, 40$ and $60 \ J \ K^{-1} \ mol^{-1}$ respectively. For the reaction $H_2 + Cl_2 \rightleftharpoons 2HCl$,with $\Delta H = +30 \ kJ$,the temperature at which the reaction will be at equilibrium is $..... \ K$.

$A$ gas (Molar mass $= 280 \ g \ mol^{-1}$) was burnt in excess $O_2$ in a constant volume calorimeter and during combustion the temperature of calorimeter increased from $298.0 \ K$ to $298.45 \ K$. If the heat capacity of calorimeter is $2.5 \ kJ \ K^{-1}$ and enthalpy of combustion of gas is $9 \ kJ \ mol^{-1}$,then the amount of gas burnt is $...... \ g$. (Nearest Integer)