The decomposition of the smog component peroxyacetyl nitrate $(PAN)$ follows a first-order reaction into peroxyacetyl radical and $NO_{2(g)}$,with a half-life of $32 \ min$.
$CH_3COONO_2 \to CH_3COO^{\bullet} + NO_2$
If the initial concentration of $PAN$ in an air sample is $5.0 \times 10^{14} \ molecules/L$,what will be the concentration after $1.5 \ hr$?

Which of the following is the correct equation for a first-order reaction?

The reaction $X \rightarrow$ products is a first order reaction. In $40 \ min$,the concentration of $X$ changes from $1.0 \ M$ to $0.25 \ M$. What is the rate of reaction when $[X] = 0.1 \ M$? $(\log 4 = 0.60)$

The following is a first-order reaction:
$N_2O_5 \text{ (solution)} \rightarrow 2 NO_2 \text{ (solution)} + \frac{1}{2} O_2 \text{ (g)}$
In this reaction,$CCl_4$ is the solvent. The rate constant is $k = 5.0 \times 10^{-4} \ s^{-1}$. The initial concentration of $N_2O_5$ is $0.25 \ mol \ L^{-1}$.
$(i)$ What will be the initial rate of reaction?
$(ii)$ Calculate the half-life $(t_{1/2})$.
$(iii)$ How much time is required to complete $75\%$ of the reaction?
$(iv)$ Calculate the concentration of $N_2O_5$ and $NO_2$ after $30 \ min$.

Which one of the following plots is correct for a first order reaction?

For a first order reaction $A_5 \rightarrow 5 B_2$,the concentration vs time plot is as shown. The half-life of the reaction is