Which of the following is the most stable complex?

Which of the following is not true for a ligand-metal complex?

Given below are two statements:
Statement $I$ : $N(CH_3)_3$ and $P(CH_3)_3$ can act as ligands to form transition metal complexes.
Statement $II$: As $N$ and $P$ are from same group,the nature of bonding of $N(CH_3)_3$ and $P(CH_3)_3$ is always same with transition metals.
In the light of the above statements,choose the most appropriate answer from the options given below:

Solubility of iodine in water is greatly increased by the addition of iodide ions because of the formation of ......

The $IR$ stretching frequencies of free $CO$ and $CO$ in $[V(CO)_6]^-$,$[Cr(CO)_6]$ and $[Mn(CO)_6]^+$ are $2143 \, cm^{-1}$,$1860 \, cm^{-1}$,$2000 \, cm^{-1}$ and $2090 \, cm^{-1}$,respectively. Then the correct statement about metal carbonyls is:

The brown ring test for $NO_2^-$ and $NO_3^-$ is due to the formation of a complex ion with the formula: