(D) For a heterogeneous equilibrium reaction involving solids and gases,the concentration or partial pressure of pure solids is taken as unity $(1)$.G

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(D) For a heterogeneous equilibrium reaction involving solids and gases,the concentration or partial pressure of pure solids is taken as unity $(1)$.Given the reaction: $ZnCO_{3(s)} \rightleftharpoons ZnO_{(s)} + CO_{2(g)}$.The equilibrium constant expression in terms of partial pressure is $K_p = \frac{P_{ZnO} \times P_{CO_2}}{P_{ZnCO_3}}$.Since $ZnCO_{3(s)}$ and $ZnO_{(s)}$ are pure solids,their partial pressures are considered as $1$.Therefore,$K_p = 1 \times P_{CO_2} / 1 = P_{CO_2}$.

Class 11 Chemistry 6-1.Equilibrium (Chemical Equilibrium)Kp and Kc Relationship

Medium

For the reaction $ZnCO_{3(s)} \rightleftharpoons ZnO_{(s)} + CO_{2(g)}$,the expression for the equilibrium constant in terms of partial pressure $(K_p)$ is .............

A
$K_p = [ZnO][CO_2] / [ZnCO_3]$
B
$K_p = P_{ZnO} \times P_{CO_2} / P_{ZnCO_3}$
C
$K_p = P^2_{ZnO} \times P_{CO_2}$
D
$K_p = P_{CO_2}$

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6-1.Equilibrium (Chemical Equilibrium)

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Kp and Kc Relationship

At equilibrium,the concentrations are $[N_2] = 3.0 \times 10^{-3} \ M$,$[O_2] = 4.2 \times 10^{-3} \ M$,and $[NO] = 2.8 \times 10^{-3} \ M$ in a sealed vessel at $800 \ K$ and $1 \ atm$ pressure. What will be $K_p$ for the given reaction?
$N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$

DifficultAIIMS 2018

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Two gaseous equilibria $SO_{2(g)} + \frac{1}{2}O_{2(g)} \rightleftharpoons SO_{3(g)}$ and $2SO_{3(g)} \rightleftharpoons 2SO_{2(g)} + O_{2(g)}$ have equilibrium constants $K_1$ and $K_2$ respectively at $298 \ K$. Which of the following relationships between $K_1$ and $K_2$ is correct?

MediumAIPMT 1989

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$1 \ mol$ $N_2$ and $3 \ mol$ $H_2$ are heated at $473 \ K$ and $100 \ atm$ pressure. At equilibrium,the number of moles of $NH_3$ is $0.5 \ mol$. Calculate the equilibrium constant $K_p$ of the given reaction: $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$

Medium

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For the reaction $PCl_{3(g)} + Cl_{2(g)} \rightleftharpoons PCl_{5(g)}$ at $250 \ ^oC$,the value of $K_c$ is $26$. The value of $K_p$ at the same temperature is .........

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The equilibrium $NH_4HS_{(s)} \rightleftharpoons NH_{3(g)} + H_2S_{(g)}$ is set up at $127 \,^oC$ in a closed vessel. The total pressure at equilibrium was $20 \,atm$. The $K_C$ for the reaction is: (in $,M^2$)

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For the reaction $ZnCO_{3(s)} \rightleftharpoons ZnO_{(s)} + CO_{2(g)}$,the expression for the equilibrium constant in terms of partial pressure $(K_p)$ is .............

Similar Questions

At equilibrium,the concentrations are $[N_2] = 3.0 \times 10^{-3} \ M$,$[O_2] = 4.2 \times 10^{-3} \ M$,and $[NO] = 2.8 \times 10^{-3} \ M$ in a sealed vessel at $800 \ K$ and $1 \ atm$ pressure. What will be $K_p$ for the given reaction?$N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$

Two gaseous equilibria $SO_{2(g)} + \frac{1}{2}O_{2(g)} \rightleftharpoons SO_{3(g)}$ and $2SO_{3(g)} \rightleftharpoons 2SO_{2(g)} + O_{2(g)}$ have equilibrium constants $K_1$ and $K_2$ respectively at $298 \ K$. Which of the following relationships between $K_1$ and $K_2$ is correct?

$1 \ mol$ $N_2$ and $3 \ mol$ $H_2$ are heated at $473 \ K$ and $100 \ atm$ pressure. At equilibrium,the number of moles of $NH_3$ is $0.5 \ mol$. Calculate the equilibrium constant $K_p$ of the given reaction: $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$

For the reaction $PCl_{3(g)} + Cl_{2(g)} \rightleftharpoons PCl_{5(g)}$ at $250 \ ^oC$,the value of $K_c$ is $26$. The value of $K_p$ at the same temperature is .........

The equilibrium $NH_4HS_{(s)} \rightleftharpoons NH_{3(g)} + H_2S_{(g)}$ is set up at $127 \,^oC$ in a closed vessel. The total pressure at equilibrium was $20 \,atm$. The $K_C$ for the reaction is: (in $,M^2$)

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At equilibrium,the concentrations are $[N_2] = 3.0 \times 10^{-3} \ M$,$[O_2] = 4.2 \times 10^{-3} \ M$,and $[NO] = 2.8 \times 10^{-3} \ M$ in a sealed vessel at $800 \ K$ and $1 \ atm$ pressure. What will be $K_p$ for the given reaction?
$N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$