For the reaction $C_{(s)} + CO_{2(g)} \rightleftharpoons 2CO_{(g)}$,if $25\%$ of $CO_2$ is converted to $CO$ at equilibrium and the total equilibrium pressure is $12 \ atm$,then the partial pressure of $CO_2$ at equilibrium will be............$atm$.

For the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$,the value of $K_c$ is $0.04$ at $250 \ ^oC$ in a $3 \ L$ vessel. If the concentration of $Cl_2$ at equilibrium is $0.15 \ M$,then the initial moles of $PCl_5$ will be ...........

The surface of copper gets tarnished by the formation of copper oxide. $N_2$ gas was passed to prevent the oxide formation during heating of copper at $1250 \ K$. However,the $N_2$ gas contains $1 \ \text{mole}\%$ of water vapour as impurity. The water vapour oxidises copper as per the reaction given below:
$2 Cu_{(s)} + H_2O_{(g)} \longrightarrow Cu_2O_{(s)} + H_{2(g)}$
$p_{H_2}$ is the minimum partial pressure of $H_2$ (in $\text{bar}$) needed to prevent the oxidation at $1250 \ K$. The value of $\ln(p_{H_2})$ is . . . . .
(Given: total pressure $= 1 \ \text{bar}$,$R = 8 \ J \ K^{-1} \ mol^{-1}$,$\ln(10) = 2.3$. $Cu_{(s)}$ and $Cu_2O_{(s)}$ are mutually immiscible.
At $1250 \ K$: $2 Cu_{(s)} + 1/2 O_{2(g)} \longrightarrow Cu_2O_{(s)}; \Delta G^\theta = -78,000 \ J \ mol^{-1}$
$H_{2(g)} + 1/2 O_{2(g)} \longrightarrow H_2O_{(g)}; \Delta G^\theta = -1,78,000 \ J \ mol^{-1}$)

For the reaction $2P_{(g)} + Q_{(g)} \rightleftharpoons R_{(g)} + S_{(g)}$; $K_C = 10^{12}$. If the initial moles of $P, Q, R, S$ are $2, 1, 7$ and $3$ moles respectively in a $1 \ L$ vessel,find the equilibrium concentration of $P$.

Observe the following equations:
$Ag^{+} + NH_3 \rightleftharpoons [Ag(NH_3)]^{+}$,$K_1 = 1.6 \times 10^3$
$[Ag(NH_3)]^{+} + NH_3 \rightleftharpoons [Ag(NH_3)_2]^{+}$,$K_2 = 6.8 \times 10^3$
The equilibrium constant for the following reaction,$Ag^{+} + 2 NH_3 \rightleftharpoons [Ag(NH_3)_2]^{+}$ is

$A$ mixture of $SO_2$ and $O_2$ at $5 \, atm$ pressure reacts $30\%$ until equilibrium is reached. Determine the total pressure of the equilibrium mixture in $atm$.
$2SO_{2(g)} + O_{2(g)} \rightleftharpoons 2SO_{3(g)}$