Which of the following buffers will have a $pH$ value greater than $7$?

Addition of sodium hydroxide solution to a weak acid $(HA)$ results in a buffer of $pH \ 6$. If ionisation constant of $HA$ is $10^{-5}$,the ratio of salt to acid concentration in the buffer solution will be

Aqueous solutions of $HNO_3$,$KOH$,$CH_3COOH$,and $CH_3COONa$ of identical concentrations are provided.
The pair$(s)$ of solutions which form a buffer upon mixing is(are):
$A$. $HNO_3$ and $CH_3COOH$
$B$. $KOH$ and $CH_3COONa$
$C$. $HNO_3$ and $CH_3COONa$
$D$. $CH_3COOH$ and $CH_3COONa$

$A$ sample of $100 \ mL$ of $0.10 \ M$ acid $HA$ $(K_a = 1 \times 10^{-5})$ is titrated with standard $0.2 \ M \ KOH$. How many $mL$ of $KOH$ will have to be added when the $pH$ in the titration flask will be $5.00$?

The $pK_a$ of $HCN$ is $9.30$. What is the $pH$ of a solution prepared by mixing $2.5 \ mol$ of $KCN$ and $2.5 \ mol$ of $HCN$ in $500 \ mL$ of water (in $.30$)?

The most important buffer in the blood consists of