In which of the following is $NH_3$ $NOT$ used?

When $NH_3$ reacts with $Cl_2$,which of the following statements are correct?
$(a)$ $NCl_3$ is formed when $Cl_2$ is in excess.
$(b)$ $N_2$ is formed when $Cl_2$ is in excess.
$(c)$ $N_2$ is formed when $NH_3$ is in excess.
$(d)$ $NCl_3$ is formed when $NH_3$ is in excess.

The most common minerals of phosphorus are

Zinc on reaction with concentrated nitric acid gives an oxide of nitrogen $(A)$. Zinc with dilute nitric acid gives another oxide of nitrogen $(B)$. Oxidation numbers of nitrogen in $(A)$ and $(B)$ are respectively:

In $P_4$ (tetrahedral) molecule:

The following are some statements related to $VA$ group hydrides:
$I$. Reducing property increases from $NH_3$ to $BiH_3$.
$II$. Tendency to donate lone pair decreases from $NH_3$ to $BiH_3$.
$III$. Thermal stability of hydrides decreases from $NH_3$ to $BiH_3$.
$IV$. Bond angle of hydrides decreases from $NH_3$ to $BiH_3$.
The correct statements are: