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(D) The conversion of primary alcohols $(R-CH_2OH)$ to aldehydes $(RCHO)$ requires a mild oxidizing agent that stops the oxidation at the aldehyde sta

Vedclass · Accepted Answer

$PCC$ (Pyridinium chlorochromate)

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(D) The conversion of primary alcohols $(R-CH_2OH)$ to aldehydes $(RCHO)$ requires a mild oxidizing agent that stops the oxidation at the aldehyde stage without further oxidizing it to a carboxylic acid. $PCC$ (Pyridinium chlorochromate) is a selective oxidizing agent that performs this specific transformation efficiently. Strong oxidizing agents like $KMnO_4$,$K_2Cr_2O_7$,and $CrO_3$ (in acidic medium) typically oxidize primary alcohols directly to carboxylic acids.

Which of the following reagents is most suitable for the conversion of $R-CH_2OH$ to $RCHO$?

Similar Questions

What is $(P)$ in the reaction given below?
$(P)$ $\xrightarrow[\text{(ii) } H_3O^{+}]{\text{(i) } CH_3MgBr} (R)$ $\xrightarrow[\text{(ii) } \Delta]{\text{(i) dil. } NaOH} \text{4-methylpent-3-en-2-one}$

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Identify the reaction shown in the image:
$C_6H_5CN \xrightarrow[(ii) H_3O^+]{(i) SnCl_2 + HCl} C_6H_5CHO$

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