The $\Delta G^o$ for the reaction $X + Y \rightleftharpoons Z$ is $-4.606 \ kcal$. The value of the equilibrium constant of the reaction at $227 \ ^oC$ is $(R = 2.0 \ cal \ mol^{-1} K^{-1})$.

  • A
    $100$
  • B
    $10$
  • C
    $2$
  • D
    $0.01$

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Find out $\ln K_{eq}$ for the formation of $NO_2$ from $NO$ and $O_2$ at $298 \ K$.
$NO_{(g)} + \frac{1}{2} O_{2(g)} \rightleftharpoons NO_{2(g)}$
Given:
$\Delta G^o_f (NO_2) = 52.0 \ kJ/mol$
$\Delta G^o_f (NO) = 87.0 \ kJ/mol$
$\Delta G^o_f (O_2) = 0 \ kJ/mol$

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Solid $KClO_4$ is taken in a container maintained at a constant pressure of $1 \, atm$. Upon heating,the following equilibrium is obtained:
$2KClO_{4(s)} \rightleftharpoons 2KCl_{(s)} + 3O_{2(g)}$
If $\Delta H^o = 25 \, kcal/mol$ and $\Delta S^o = 50 \, cal/K \cdot mol$,at what temperature will equilibrium be established in the container (in $, K$)? (Ignore variation of $\Delta H^o$ and $\Delta S^o$ with temperature.)

Write the formula relating the equilibrium constant $K$ and $\Delta G^{\circ}$.

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For the reaction $A_{(g)} \rightarrow B_{(g)},$ the value of the equilibrium constant at $300 \ K$ and $1 \ atm$ is equal to $100.0.$ The value of $\Delta_{r}G^{\circ}$ for the reaction at $300 \ K$ and $1 \ atm$ in $J \ mol^{-1}$ is $-xR,$ where $x$ is ........... (Rounded off to the nearest integer) ($R = 8.31 \ J \ mol^{-1} K^{-1}$ and $\ln 10 = 2.3$)

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