Write the mechanism of the acid dehydration of ethanol to yield ethene.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The dehydration of ethanol to ethene proceeds via a $\beta$-elimination mechanism in three steps:
Step-$1$: Protonation of ethanol to form ethyl oxonium ion.
$CH_3CH_2OH + H^+ \rightleftharpoons CH_3CH_2OH_2^+$
Step-$2$: Formation of carbocation. This is the slow,rate-determining step where the $C-O$ bond breaks and water is eliminated.
$CH_3CH_2OH_2^+ \rightleftharpoons CH_3CH_2^+ + H_2O$
Step-$3$: Formation of ethene by elimination of a proton. The carbocation loses a $\beta$-proton to form ethene.
$CH_3CH_2^+ \rightleftharpoons CH_2=CH_2 + H^+$

Explore More

Similar Questions

Methanol and ethanol are soluble in water due to......

Match the reagents in Column-$I$ with the major products obtained from the reaction of $Butan-1-ol$ in Column-$II$.
Column-$I$ (Reagents)Column-$II$ (Products)
$A$. $HCl + ZnCl_2$$i$. $CH_3CH=CHCH_3$
$B$. $HBr$$ii$. $CH_3CH_2CH_2CH_2Cl$
$C$. $SOCl_2$$iii$. $CH_3CH_2CH_2CH_2Br$
$D$. $H_2SO_4, \Delta$$iv$. $CH_3CH_2CH_2CH_2Cl$

Which of the following alcohols is not oxidized by $PCC$?

In $CH_3CH_2OH \xrightarrow{X} CH_2 = CH_2 + H_2O$ at $350 \ ^oC$; $'X'$ is

In the given pairs of alcohols,in which pair is the second alcohol more reactive than the first towards hydrogen bromide $(HBr)$?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo