Explain the bonding in metal carbonyls.

(N/A) Homoleptic carbonyls are those compounds in which only carbonyl ligands are present.
These compounds are formed by most of the transition metals. These carbonyls have simple,well-defined structures. $[Ni(CO)_4]$,$[Fe(CO)_5]$,and $[Cr(CO)_6]$ have tetrahedral,trigonal bipyramidal,and octahedral structures,respectively.
Decacarbonyldimanganese $(0)$ is formed by the $Mn-Mn$ bond between two square pyramidal $[Mn(CO)_5]$ units. In octacarbonyldicobalt $(0)$,there is a $Co-Co$ bond bridged by two $CO$ groups.
In metal carbonyls,the metal-carbon bond possesses both $\sigma$ and $\pi$ character. The $M-C$ $\sigma$ bond is formed by the donation of lone pairs of electrons from the carbonyl carbon into the vacant orbitals of the metal.
The $M-C$ $\pi$ bond is formed by the donation of electrons from the filled $d$-orbitals of the metal into the vacant $\pi^*$ antibonding orbitals of $CO$. The metal-to-ligand bonding creates a synergic effect,which strengthens the bond between the metal and $CO$.