Match the reactants in Column-$I$ with their products in Column-$II$.
Column-$I$ (Reactants)Column-$II$ (Products)
$(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$$(i)$ Phenol
$(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$$(ii)$ $2,4,6$-Trinitrophenol
$(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$$(iii)$ $2,4$-Dinitrophenol
$(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$$(iv)$ $p$-Nitrophenol

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A-IV, B-I, C-III, D-II) The reaction of haloarenes with nucleophiles depends on the presence of electron-withdrawing groups (like $-NO_2$) on the benzene ring. These groups activate the ring towards nucleophilic substitution.
$(A)$ $p$-Nitrochlorobenzene reacts with $NaOH$ at $443 \ K$ to give $p$-nitrophenol. Thus,$(A \rightarrow iv)$.
$(B)$ Chlorobenzene is least reactive and requires harsh conditions $(623 \ K, 300 \ atm)$ to form phenol. Thus,$(B \rightarrow i)$.
$(C)$ $2,4$-Dinitrochlorobenzene is more reactive than $p$-nitrochlorobenzene and reacts at $368 \ K$ to give $2,4$-dinitrophenol. Thus,$(C \rightarrow iii)$.
$(D)$ $2,4,6$-Trinitrochlorobenzene is highly reactive and can be hydrolyzed by warm water to give $2,4,6$-trinitrophenol (picric acid). Thus,$(D \rightarrow ii)$.
The correct matching is: $(A$ $\rightarrow iv, B$ $\rightarrow i, C$ $\rightarrow iii, D$ $\rightarrow ii)$.

Explore More

Similar Questions

Which reaction shows the correct major product?

The rate of reaction of $NaOH$ with the following compounds follows the order:
$I$: $1$-fluoro-$2$-nitrobenzene
$II$: $1$-fluoro-$3$-nitrobenzene
$III$: $1$-fluoro-$4$-nitrobenzene

What is formed when chlorobenzene reacts with ammonia in the presence of $Cu_2O$ in xylene at $570 \ K$?

Given below are two statements: one is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$.
Assertion $(A)$ : Chlorine is an electron withdrawing group but it is ortho,para directing in electrophilic aromatic substitution.
Reason $(R)$ : Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution,however due to the more pronounced resonance effect,the halogen stabilises the carbocation at ortho and para positions.
In the light of the above statements,choose the most appropriate answer from the options given below :

The reaction between chlorobenzene and chloral in the presence of concentrated sulphuric acid produces $:$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo