$(i) X(g) \rightleftharpoons Y(g) + Z(g), K_{p1} = 3$
$(ii) A(g) \rightleftharpoons 2B(g), K_{p2} = 1$
If the degree of dissociation and initial concentration of both the reactants $X(g)$ and $A(g)$ are equal,then the ratio of the total pressure at equilibrium $\left( \frac{p_1}{p_2} \right)$ is equal to $x : 1$. The value of $x$ is $......$ (Nearest integer)

Two equilibria,$AB \rightleftharpoons A^{+} + B^{-}$ and $AB + B^{-} \rightleftharpoons AB_2^-$,are simultaneously maintained in a solution with equilibrium constants $K_1$ and $K_2$ respectively. The ratio of $[A^{+}]$ to $[AB_2^-]$ in the solution is

One mole of $N_2O_{4(g)}$ at $300 \ K$ is kept in a closed container under $1 \ atm$ pressure. It is heated to $600 \ K$ when $20 \%$ of $N_2O_{4(g)}$ decomposes to $NO_{2(g)}$. The resultant pressure at $600 \ K$ is $..... \ atm$.

Given the equilibrium constants for the following reactions:
$(1) \ CO_{2(g)} + H_{2(g)} \rightleftharpoons CO_{(g)} + H_2O_{(g)} \ ; \ K_1$
$(2) \ CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)} \ ; \ K_2$
What is the relationship between $K_1$ and $K_2$?

For the reaction,$0.5 C_{(s)} + 0.5 CO_{2(g)} \rightleftharpoons CO_{(g)}$,the equilibrium pressure is $12 \ atm$. If $CO_2$ conversion is $50 \%$,the value of $K_p$,in $atm$,is:

At $473 \ K$, equilibrium constant $K_{c}$ for decomposition of phosphorus pentachloride, $PCl_{5}$, is $8.3 \times 10^{-3}$. If decomposition is depicted as,
$PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}, \Delta_{r}H^{\Theta} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if $(i)$ more $PCl_{5}$ is added $(ii)$ pressure is increased $(iii)$ the temperature is increased?