CH_3NH_2 + CHCl_3 + KOH rightarrow Nitrogen c | vedclass

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Question

(C) The given reaction is the $Carbylamine$ reaction (also known as the isocyanide test). Primary amines (both aliphatic and aromatic) react with chlo

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$CH_3-N \equiv C$

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(C) The given reaction is the $Carbylamine$ reaction (also known as the isocyanide test). Primary amines (both aliphatic and aromatic) react with chloroform $(CHCl_3)$ and alcoholic potassium hydroxide $(KOH)$ to form isocyanides (carbylamines),which have a foul smell. The balanced chemical equation is: $CH_3NH_2 + CHCl_3 + 3KOH \rightarrow CH_3NC + 3KCl + 3H_2O$. The nitrogen-containing compound formed is methyl isocyanide $(CH_3NC)$,which is represented as $CH_3-N \equiv C$ or $CH_3-N^{+} \equiv C^{-}$.

$CH_3NH_2 + CHCl_3 + KOH \rightarrow$ Nitrogen containing compound $+ KCl + H_2O$. The nitrogen-containing compound is:

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