$10 \ g$ each of $NH_3, N_2, Cl_2$ and $H_2S$ are expanded isothermally and reversibly at the same temperature. Identify the gas that performs maximum work.

For the reaction $CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$ at $977 \ ^oC$,given $\Delta H = 176 \ kJ \ mol^{-1}$,the value of $\Delta E$ is ............. $kJ$.

$28.0 \, L$ of $CO_2$ is produced on complete combustion of $16.8 \, L$ gaseous mixture of ethene $(C_2H_4)$ and methane $(CH_4)$ at $25^{\circ}C$ and $1 \, atm$. Heat evolved during the combustion process is $......... \, kJ$.
Given :
$\Delta H_C(CH_4) = -900 \, kJ \, mol^{-1}$
$\Delta H_C(C_2H_4) = -1400 \, kJ \, mol^{-1}$

The heat of reaction for $C_6H_{12}O_{6(s)} + 6O_{2(g)} \to 6CO_{2(g)} + 6H_2O_{(l)}$ at constant pressure is $-651 \, kcal$ at $17 \, ^oC$. Calculate the heat of reaction at constant volume at $17 \, ^oC$ in $kcal$.

The heat evolved in the combustion of methane is given by the following equation: $CH_{4(g)} + 2O_{2(g)} \to CO_{2(g)} + 2H_2O_{(l)}$; $\Delta H = -890.3 \ kJ$. How many grams of methane would be required to produce $445.15 \ kJ$ of heat of combustion?

In a constant volume calorimeter,$3.5 \ g$ of a gas with molecular weight $28$ was burnt in excess oxygen at $298.0 \ K$. The temperature of the calorimeter was found to increase from $298.0 \ K$ to $298.45 \ K$ due to the combustion process. Given that the heat capacity of the calorimeter is $2.5 \ kJ \ K^{-1}$,the numerical value for the enthalpy of combustion of the gas in $kJ \ mol^{-1}$ is