$A$ coordination compound is made of $Co^{3+}$,$NH_3$,and $Cl^{-}$. $A$ $0.1 \ M$ solution of this complex when treated with excess silver nitrate gave no precipitate. The formula of the complex and secondary valency of metal are respectively.

  • A
    $[Co(NH_3)_3 Cl_3], 6$
  • B
    $[Co(NH_3)_5 Cl]Cl_2, 6$
  • C
    $[Co(NH_3)_3 Cl_3], 3$
  • D
    $[Co(NH_3)_4 Cl_2]Cl, 6$

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Identify the hybridization of the central metal atom in the $[Fe(CO)_5]$ complex.

The magnetic moment of the high spin complex is $5.92 \ BM$. What is the electronic configuration?

Which of the following complexes is tetrahedral as well as diamagnetic?

On the basis of valence bond theory,discuss the geometrical shapes and magnetic properties of the following $4$-coordinated complexes:
$(i)$ $[NiCl_{4}]^{2-}$
$(ii)$ $[Ni(CN)_{4}]^{2-}$
$(iii)$ $[Ni(CO)_{4}]$
$(iv)$ $MnO_{4}^{-}$

Match List-$I$ with List-$II$.
List-$I$ List-$II$
$A. Ni(CO)_4$ $I. sp^3$
$B. [Ni(CN)_4]^{2-}$ $II. sp^3d^2$
$C. [Co(CN)_6]^{3-}$ $III. d^2sp^3$
$D. [CoF_6]^{3-}$ $IV. dsp^2$

Choose the correct answer from the options given below.

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