$A$ and $B$ on mixing form an ideal solution at room temperature. Which of the following options is correct for this process?

  • A
    $\Delta G$$\Delta S_{\text{system}}$$\Delta S_{\text{surroundings}}$$\Delta H$
    $-$$+$$+$$+$
  • B
    $\Delta G$$\Delta S_{\text{system}}$$\Delta S_{\text{surroundings}}$$\Delta H$
    $+$$+$$0$$+$
  • C
    $\Delta G$$\Delta S_{\text{system}}$$\Delta S_{\text{surroundings}}$$\Delta H$
    $-$$+$$0$$0$
  • D
    $\Delta G$$\Delta S_{\text{system}}$$\Delta S_{\text{surroundings}}$$\Delta H$
    $-$$-$$+$$+$

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The vapour pressures of chloroform $(CHCl_3)$ and dichloromethane $(CH_2Cl_2)$ at $298 \ K$ are $200 \ mmHg$ and $415 \ mmHg$,respectively. An ideal solution is prepared by mixing $59.75 \ g$ of $CHCl_3$ and $21.25 \ g$ of $CH_2Cl_2$. The mole fractions of chloroform and dichloromethane in the vapour phase,respectively,are:

Which of the following pairs of liquids shows a positive deviation from Raoult's law?

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