For the reaction $PCl_5(g) \rightleftarrows PCl_3(g) + Cl_2(g)$,which condition is correct?

  • A
    $\Delta H < 0, \Delta S < 0$
  • B
    $\Delta H > 0, \Delta S < 0$
  • C
    $\Delta H = 0, \Delta S < 0$
  • D
    $\Delta H > 0, \Delta S > 0$

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For a reaction $A_{(s)} \rightleftharpoons B_{(s)} + C_{(g)}$,the set of all correct statements are:
$(a) \ K$ is independent of $[A]$.
$(b) \ K$ is dependent on partial pressure of $C$ at a given temperature.
$(c) \ \Delta H$ will be independent of temperature.
$(d) \ \Delta H$ is independent of the catalyst addition.

In a $10 \ L$ vessel,$1 \ mol$ each of $PCl_5$ and $PCl_3$ are present. If the vessel is heated,some $PCl_5$ dissociates. What are the concentrations of $PCl_5$,$PCl_3$,and $Cl_2$ at equilibrium,respectively?

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Consider the following reversible first-order reaction of $X$ at an initial concentration $[X]_{0}$. The values of the rate constants are $K_{f} = 2 \ s^{-1}$ and $K_{b} = 1 \ s^{-1}$.
$X \underset{K_{b}}{\stackrel{K_{f}}{\rightleftharpoons}} Y$
Which of the following plots correctly represents the concentration of $X$ and $Y$ as a function of time?

Match the items in List-$X$ with List-$Y$ and select the correct option.
List-$X$ List-$Y$
$(A)$ Active mass $(i)$ $\Delta n = 0$
$(B)$ Equilibrium constant $(ii)$ Molar concentration
$(C)$ $A + \text{Heat} \rightleftharpoons B$ $(iii)$ Van't Hoff equation
$(D)$ $2A_{(g)} + B_{(g)} \rightleftharpoons 3C_{(g)}$ $(iv)$ Favoured by increase in temperature
$(v)$ Chemical equilibrium

For a given reaction,$2 A \rightleftharpoons B + C$,the equilibrium constant is $2 \times 10^{-3}$. If at any given time the composition of the reaction mixture is $[A]=[B]=[C]=6 \times 10^{-5} \ M$; predict in which direction the reaction will proceed and the correct value for reaction quotient.

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