Calculate the heat change for the reaction $4NH_3(g) + 3O_2(g) \rightarrow 2N_2(g) + 6H_2O(l)$ in $kJ$. The enthalpies of formation of $NH_3(g)$ and $H_2O(l)$ at $298 \ K$ are $-46.0 \ kJ \ mol^{-1}$ and $-286.0 \ kJ \ mol^{-1}$ respectively.

  • A
    $-1932$
  • B
    $-2011$
  • C
    $-1532$
  • D
    $-1281$

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The heat of solution of $Na_2SO_{4(s)}$ and $Na_2SO_4 \cdot 10H_2O_{(s)}$ are $-2.34 \ kJ \ mol^{-1}$ and $78.87 \ kJ \ mol^{-1}$ respectively. The heat of hydration of $Na_2SO_{4(s)}$ is:

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On the basis of the following equations,the heat of dimerisation of $NO_2$ will be:
$(i) \ N_2 + 2O_2 \to 2NO_2, \Delta H = 67.9 \ kJ$
$(ii) \ N_2 + 2O_2 \to N_2O_4, \Delta H = 9.3 \ kJ$

Enthalpies of formation of $CO_{(g)}$,$CO_{2(g)}$,$N_2O_{(g)}$ and $N_2O_{4(g)}$ are $-110$,$-393$,$81$ and $9.7 \, kJ \, mol^{-1}$ respectively. Find the value of $\Delta_r H$ for the reaction:
$N_2O_{4(g)} + 3 CO_{(g)} \rightarrow N_2O_{(g)} + 3 CO_{2(g)}$

The standard heats of formation in $kcal \ mol^{-1}$ of $NO_{2(g)}$ and $N_2O_{4(g)}$ are $8.0$ and $2.0$ respectively. The heat of dimerization of $NO_2$ in $kcal$ for the reaction $2NO_{2(g)} \rightarrow N_2O_{4(g)}$ is:

Energy required to dissociate $4 \ g$ of gaseous hydrogen into free gaseous atoms is $208 \ kcal$ at $25 \ ^oC$. The bond energy of $H-H$ bond will be

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