Which thermochemical reaction is correct?

The heat of solution of anhydrous $CuSO_4$ and $CuSO_4 \cdot 5 H_2 O$ are $-70 \ kJ \ mol^{-1}$ and $+12 \ kJ \ mol^{-1}$ respectively. The heat of hydration of $CuSO_4$ to $CuSO_4 \cdot 5 H_2 O$ is $-x \ kJ$. The value of $x$ is:

What will be the amount of heat evolved by burning $0.4 \ mol$ of methane? (Given heats of formation of $CH_4$,$CO_2$,and $H_2O$ are $-75$,$-400$,and $-240 \ kJ \ mol^{-1}$ respectively) ..... $kJ$

Given the following thermochemical equations:
$1) \ C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)}, \Delta H = -787 \ kJ$
$2) \ H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(l)}, \Delta H = -286 \ kJ$
$3) \ C_2H_{2(g)} + \frac{5}{2} O_{2(g)} \rightarrow 2CO_{2(g)} + H_2O_{(l)}, \Delta H = -1310 \ kJ$
Calculate the enthalpy of formation of acetylene $(C_2H_{2(g)})$ in $kJ \ mol^{-1}$.

What will be the $C-H$ bond enthalpy if:
$CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)};$ $\Delta H = -890 \, kJ$
$CO_{2(g)} \rightarrow C_{(graphite)} + O_{2(g)};$ $\Delta H = 393 \, kJ$
$2H_2O_{(l)} \rightarrow 2H_{2(g)} + O_{2(g)};$ $\Delta H = 571 \, kJ$
$2H_{2(g)} \rightarrow 4H_{(g)};$ $\Delta H = 871 \, kJ$
$C_{(graphite)} \rightarrow C_{(g)};$ $\Delta H = 716 \, kJ$

If the value of $\Delta H_{O-H}$ is $109 \ kcal \ mol^{-1}$,then the formation of one mole of water from $H_{(g)}$ and $O_{(g)}$ is associated with: