The heat of combustion of sucrose $(C_{12}H_{22}O_{11})$ is $1350 \ kcal \ mol^{-1}$. How much heat (in $kcal$) will be released by the combustion of $17.1 \ g$ of sucrose (in $.5$)?

Calculate $\Delta H_f^o$ of $SiH_2$ from the following reactions:
$Si_2H_{6(g)} + H_{2(g)} \to 2SiH_{4(g)}, \Delta H = -11.7 \ kJ/mol$
$SiH_{4(g)} \to SiH_{2(g)} + H_{2(g)}, \Delta H = +239.7 \ kJ/mol$
$\Delta H_f^o(Si_2H_{6(g)}) = 80.3 \ kJ/mol$

Match the following:

$A$. Isothermal process	$i$. $q = \Delta U$
$B$. Adiabatic process	$ii$. $W = - P \times \Delta V$
$C$. Isobaric process	$iii$. $W = \Delta U$
$D$. Isochoric process	$iv$. $W = - nRT \ln \left(\frac{v_f}{v_i}\right)$

Consider the following statements:
Statement-$I$: During isothermal expansion of an ideal gas,its enthalpy decreases.
Statement-$II$: When $2.0 \ L$ of an ideal gas expands isothermally into vacuum,$\Delta U = 0$.

Calculate the enthalpy change when $50 \ mL$ of $0.01 \ M$ $Ca(OH)_2$ reacts with $25 \ mL$ of $0.01 \ M$ $HCl$. Given that $\Delta H^o$ for neutralization of a strong acid and a strong base is $-13.7 \ kcal \ mol^{-1}$. (Note: The provided value in the prompt $140 \ kcal \ mol^{-1}$ is physically incorrect for neutralization; using standard value $-13.7 \ kcal \ mol^{-1}$ for calculation). (in $kcal$)

The heat associated with the combustion of liquid benzene at constant volume is $-3268 \ kJ \ mol^{-1}$. Calculate the change in enthalpy when this reaction occurs at $300 \ K$ $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$.