The enthalpy of formation of ammonia is $-46.0 \ kJ \ mol^{-1}$. The enthalpy change for the reaction $2NH_{3(g)} \rightarrow N_{2(g)} + 3H_{2(g)}$ is ............... $kJ \ mol^{-1}$.

  • A
    $46$
  • B
    $92$
  • C
    $-23$
  • D
    $-92$

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Using the data provided,calculate the bond energy $(kJ \ mol^{-1})$ of a $C \equiv C$ bond in $C_{2}H_{2}$. (Take the bond energy of a $C-H$ bond as $350 \ kJ \ mol^{-1}$)
$2C_{(s)} + H_{2(g)} \longrightarrow C_{2}H_{2(g)} \quad \Delta H = 225 \ kJ \ mol^{-1}$
$2C_{(s)} \longrightarrow 2C_{(g)} \quad \Delta H = 1410 \ kJ \ mol^{-1}$
$H_{2(g)} \longrightarrow 2H_{(g)} \quad \Delta H = 330 \ kJ \ mol^{-1}$

The bond energies of $C-C$,$C=C$,$H-H$,and $C-H$ bonds are $350$,$600$,$400$,and $410 \ kJ \cdot mol^{-1}$ respectively. The heat of hydrogenation of ethylene $(C_2H_4)$ is ... $kJ \cdot mol^{-1}$.

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Write notes on diatomic molecules and polyatomic molecules with respect to bond dissociation enthalpy.

For the reaction $2H_{2(g)} + O_{2(g)} \to 2H_2O_{(l)}$,the enthalpy change is $\Delta H = -571 \ kJ$. If the $H-H$ bond energy is $435 \ kJ \ mol^{-1}$ and the $O=O$ bond energy is $498 \ kJ \ mol^{-1}$,calculate the average bond energy of the $O-H$ bond in $kJ \ mol^{-1}$.

Given the thermochemical reactions:
$C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta H = -110.5 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta H = -283.2 \ kJ$
Calculate the heat of reaction for $C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}$ in $kJ$.

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