The enthalpy of vaporization of a liquid at $500 \, K$ and $1 \, atm$ pressure is $10 \, kcal \, mol^{-1}$. The change in internal energy $(\Delta U)$ for $3 \, moles$ of the liquid at the same temperature and pressure is ............ $kcal$.

One mole of an ideal gas for which $C_v = (3/2)R$ is heated at a constant pressure of $1 \ atm$ from $25 \ ^oC$ to $100 \ ^oC$. The value of $\Delta H$ is $...... \ cal$.

For the reaction $Br_{2(l)} + Cl_{2(g)} \rightarrow 2BrCl_{(g)}$,the enthalpy change is $\Delta H = 30 \ kJ/mol$ and the entropy change is $\Delta S = 105 \ J/mol \cdot K$. The temperature at equilibrium is $...... \ K$.

The value of $\Delta H$ for cooling $2 \ mol$ of an ideal monoatomic gas from $225^{\circ} C$ to $125^{\circ} C$ at constant pressure will be [given $C_{p} = \frac{5}{2} R$]. (in $R$)

Calculate the enthalpy change on freezing of $1.0 \ mol$ of water at $10.0^{\circ} C$ to ice at $-10.0^{\circ} C$. Given: $\Delta_{fus} H = 6.03 \ kJ \ mol^{-1}$ at $0^{\circ} C$,$C_p [H_2 O_{(l)}] = 75.3 \ J \ mol^{-1} \ K^{-1}$,$C_p [H_2 O_{(s)}] = 36.8 \ J \ mol^{-1} \ K^{-1}$.

Calculate the work done in $J$ when $63.50 \ g$ of $Zn$ is dissolved in an open beaker with hydrochloric acid at $300 \ K$. (Atomic mass of $Zn = 63.5 \ amu$)