$A$ few drops of $KMnO_4$ solution are added to an acidic solution containing an anion. Which of the following,if present,will $NOT$ cause a change in the color of the $KMnO_4$ solution?

Match the following types of reactions in List-$I$ with their corresponding unbalanced equations in List-$II$.

List-$I$ (Type of reaction)	List-$II$ (Unbalanced equation)
$A$. Combination reaction	$(i)$ $AgNO_3 + CaCl_2 \longrightarrow AgCl + Ca(NO_3)_2$
$B$. Decomposition reaction	$(ii)$ $Cl_2 \longrightarrow Cl^- + ClO_3^-$
$C$. Disproportionation reaction	$(iii)$ $Mg + N_2 \longrightarrow Mg_3N_2$
$D$. Displacement reaction	$(iv)$ $KClO_3 \xrightarrow{\Delta} KCl + O_2$

Assign $A, B, C, D$ from the given type of reaction:
$2FeCl_3 + 3KI \longrightarrow 2FeCl_2 + I_2 + 2KCl$
$I_2 + KI \longrightarrow KI_3$
Identify the observation for the product $KI_3$ in the reaction $FeCl_3 + KI \longrightarrow Fe^{2+}(aq.) + KI_3$.

Which of the following reactions are redox reactions?
$I. \, Cr_2O_7^{2-} + 2OH^- \to 2CrO_4^{2-} + H_2O$
$II. \, Zn + CuSO_4 \to ZnSO_4 + Cu$
$III. \, 2MnO_4^- + 3Mn^{2+} + 4OH^- \to 5MnO_2 + 2H_2O$
$IV. \, 2Cu^+ \to Cu + Cu^{2+}$

Identify the substance oxidised,reduced,oxidising agent,and reducing agent for each of the following reactions:
$(a)$ $2AgBr_{(s)} + C_6H_6O_{2(aq)} \to 2Ag_{(s)} + 2HBr_{(aq)} + C_6H_4O_{2(aq)}$
$(b)$ $HCHO_{(l)} + 2[Ag(NH_3)_2]^+_{(aq)} + 3OH^-_{(aq)} \to 2Ag_{(s)} + HCOO^-_{(aq)} + 2NH_{3(aq)} + 2H_2O_{(l)}$
$(c)$ $HCHO_{(l)} + 2Cu^{2+}_{(aq)} + 5OH^-_{(aq)} \to Cu_2O_{(s)} + HCOO^-_{(aq)} + 3H_2O_{(l)}$
$(d)$ $N_2H_{4(l)} + 2H_2O_{2(l)} \to N_{2(g)} + 4H_2O_{(l)}$
$(e)$ $Pb_{(s)} + PbO_{2(s)} + 2H_2SO_{4(aq)} \to 2PbSO_{4(s)} + 2H_2O_{(l)}$

How much volume of $5 \ M$ $HNO_3$ is required to oxidize $16 \ g$ of $Fe^{+2}$ if $HNO_3$ is converted into $NO$? (Answer in $mL$)