The following graph shows the variation of rate constant $(k)$ with temperature $(T)$. Which graph follows the Arrhenius equation?

  • A
    Option A
  • B
    Option B
  • C
    Option C
  • D
    Option D

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The rate constant for the first order decomposition of $H_{2}O_{2}$ is given by the following equation:
$\log k = 14.34 - 1.25 \times 10^{4} \, K / T$
Calculate $E_{a}$ for this reaction and at what temperature will its half-period be $256 \, min$?

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The reaction $A \xrightarrow{K} \text{Product}$ is zero order while the reaction $B \xrightarrow{K} \text{Product}$ is first order. For what initial concentration of $A$,the half-lives of the two reactions will be equal?

$A$ substance $S$ undergoes two reactions under similar reaction conditions:
$\mathop S\limits_{(2.0 \ M)} \xrightarrow{K_0} X$ (zero order)
$\mathop S\limits_{(2.0 \ M)} \xrightarrow{K_2} Y$ (second order)
The time taken for the concentration of $S$ to become half is $40 \ s$ and $10 \ s$ for the zero-order and second-order reactions,respectively. What is the value of the ratio $K_0 / K_2$?

Match the column $I$ with column $II$ :
$a$. Rate constant for first order reaction$i$. $mol \ lit^{-1} \sec^{-1}$
$b$. Molarity$ii$. $\frac{k \times 1000}{M}$
$c$. Rate constant for zero order reaction$iii$. $second^{-1}$
$d$. Limiting molar conductivity$iv$. $\frac{\text{moles of solute}}{\text{Volume of solution (lit)}}$

The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two-step process shown below:
$O_{3(g)} + Cl_{(g)}^{\bullet} \to O_{2(g)} + ClO_{(g)}^{\bullet}$ ..... $(i)$ $K_i = 5.2 \times 10^9 \ L \ mol^{-1} \ s^{-1}$
$ClO_{(g)}^{\bullet} + O_{(g)}^{\bullet} \to O_{2(g)} + Cl_{(g)}^{\bullet}$ ..... $(ii)$ $K_{ii} = 2.6 \times 10^{10} \ L \ mol^{-1} \ s^{-1}$
The closest rate constant for the overall reaction
$O_{3(g)} + O_{(g)}^{\bullet} \to 2O_{2(g)}$ is ........... $L \ mol^{-1} \ s^{-1}$

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