For the reaction $2NO_{(g)} + O_{2_{(g)}} \rightarrow 2NO_{2_{(g)}}$,the volume of the reaction vessel is suddenly reduced to half of its original volume. If the reaction is first order with respect to $O_2$ and second order with respect to $NO$,the rate of the reaction will:

  • A
    Increase $8$ times its initial value.
  • B
    Increase $4$ times its initial value.
  • C
    Become $1/4$ of its initial value.
  • D
    Become $1/8$ of its initial value.

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For the non-stoichiometric reaction $2A + B \rightarrow C + D,$ the following kinetic data were obtained in three separate experiments,all at $298 \, K.$
Initial Concentration $(A)$ Initial Concentration $(B)$ Initial rate of formation of $C$ $(mol \, L^{-1} \, s^{-1})$
$0.1 \, M$ $0.1 \, M$ $1.2 \times 10^{-3}$
$0.1 \, M$ $0.2 \, M$ $1.2 \times 10^{-3}$
$0.2 \, M$ $0.1 \, M$ $2.4 \times 10^{-3}$

The rate law for the formation of $C$ is:

With the help of an example,explain what is meant by a pseudo first order reaction.

The alkaline hydrolysis of an ester is a ........ reaction.

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For a reaction,$I^{-} + OCl^{-} \to IO^{-} + Cl^{-}$ in an aqueous medium,the rate of reaction is given by $\frac{d[IO^{-}]}{dt} = k[I^{-}][OCl^{-}]$. The overall order of reaction is

Consider the following reactions:
$A$ $\rightarrow P_1; B$ $\rightarrow P_2; C$ $\rightarrow P_3; D$ $\rightarrow P_4$
The orders of the above reactions are $a, b, c,$ and $d,$ respectively. The following graph is obtained when $\log[\text{rate}]$ vs. $\log[\text{conc.}]$ are plotted:
Among the following,the correct sequence for the order of the reactions is:

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