For the reaction $2NO_{2(g)} \rightleftharpoons 2NO_{(g)} + O_{2(g)}$,the equilibrium constant $K_c = 1.8 \times 10^{-6}$ at $184 \, ^\circ C$. Comparing $K_p$ and $K_c$ at $184 \, ^\circ C$,we find that:

  • A
    $K_p < K_c$
  • B
    $K_p > K_c$
  • C
    $K_p$ depends on the total gas pressure,being either less than or equal to $K_c$.
  • D
    $K_p = K_c$

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For the reaction $PCl_{3(g)} + Cl_{2(g)} \rightleftharpoons PCl_{5(g)}$,the value of $K_p$ at $250 \ ^oC$ is $0.61 \ atm^{-1}$. The value of $K_c$ at this temperature will be .... $(mol \ L^{-1})$.

$(i)$ $\frac{1}{2}N_{2(g)} + \frac{3}{2}H_{2(g)} \rightleftharpoons NH_{3(g)}$ at $298 \ K$ has $\Delta G^{\Theta} = -16.5 \ kJ \ mol^{-1}$. Find $K_p$.
$(ii)$ At $298 \ K$,for $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$,calculate $K_p$ and $\Delta G^{\Theta}$.

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For a gaseous reaction $pA + qB \rightleftharpoons qC + pD$,which of the following relationships is true?

For the reaction $SO_{2(g)} + \frac{1}{2}O_{2(g)} \rightleftharpoons SO_{3(g)}$,the relationship is given by $K_P = K_C(RT)^x$. Find the value of $x$.

At $1990 \ K$ and $1 \ atm$ pressure,there are equal number of $Cl_2$ molecules and $Cl$ atoms in the reaction mixture. The value $K_P$ for the reaction $Cl_{2(g)} \rightleftharpoons 2Cl_{(g)}$ under the above conditions is $x \times 10^{-1}$. The value of $x$ is ..........
(Rounded off to the nearest integer)

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