For the decomposition reaction $N_2O_4 \rightleftharpoons 2NO_2$ at constant temperature,the equilibrium constant is given by $K_p = \frac{4x^2P}{1 - x^2}$,where $P$ is the total pressure and $x$ is the degree of dissociation. Which of the following statements is correct?

  • A
    $K_p$ increases with an increase in $P$.
  • B
    $K_p$ increases with an increase in $x$.
  • C
    $K_p$ decreases with a decrease in $x$.
  • D
    $K_p$ remains constant with changes in $P$ and $x$.

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For the reaction $2AB_{(g)} \rightleftharpoons 2A_{(g)} + B_{2(g)}$,$AB$ dissociates. If the initial pressure of $AB$ is $500 \, mm$ and the total pressure at equilibrium is $625 \, mm$,calculate $K_p$ for the reaction. Assume constant volume.

For the reaction $N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$,$K_p = 0.492 \ atm$ at $300 \ K$. $K_c$ for the reaction at same temperature is . . . . . . $\times 10^{-2}$. (Given: $R = 0.082 \ L \ atm \ mol^{-1} \ K^{-1}$)

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