Mixing $1 \ mol$ of heptane $(V.P = 92 \ mm \ Hg)$ with $4 \ mol$ of octane $(V.P = 31 \ mm \ Hg)$ forms an ideal solution. The vapor pressure of the solution will be .......... $mm \ Hg$. (in $.2$)

  • A
    $51$
  • B
    $27$
  • C
    $33$
  • D
    $43$

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Explain non-ideal solutions and the occurrence of positive and negative deviations in non-ideal solutions.

Two liquids $A$ and $B$ form an ideal solution. When they are mixed in a molar ratio of $1:1$,the vapor pressure of the solution at $300 \ K$ is $400 \ mm \ Hg$. When they are mixed in a molar ratio of $1:2$,the vapor pressure of the solution at the same temperature is $350 \ mm \ Hg$. The vapor pressures of pure liquids $A$ and $B$ are respectively:

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$A$ solution of two miscible liquids showing negative deviation from Raoult's law will have :

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