What is the relationship between the osmotic pressures of $6.00 \ g \ L^{-1}$ $CH_3COOH$ $(\pi_1)$ and $7.45 \ g \ L^{-1}$ $KCl$ $(\pi_2)$ solutions?

Arrange the following solutions according to decreasing order of osmotic pressure under similar conditions of temperature,assuming complete dissociation:
$A. 0.2 \ m \ KCl$
$B. 0.3 \ m \ MgSO_4$
$C. 0.1 \ m \ BaCl_2$
$D. 0.5 \ m \ Al_2(SO_4)_3$

Given below are two statements:
Statement $I$: $H_2O$ molecules move from the chamber $1$ to chamber $2$.
Statement $II$: The osmotic pressure of a solution prepared by dissolving $50 \text{ mg}$ of potassium sulphate (molar mass = $174 \text{ g/mol}$) in $2 \text{ L}$ of water (at $27^{\circ}C$) is $0.0107 \text{ bar}$. (Given: $R = 0.083 \text{ dm}^3 \text{ bar K}^{-1} \text{ mol}^{-1}$ and assume complete dissociation of electrolyte).
In the light of the above statements, choose the correct answer from the options given below:

Equal volumes of $0.2 \ M$ urea and $0.2 \ M$ glucose are mixed. The mixture will have

Calculate the mass of a non-volatile solute dissolved in $0.3 \text{ dm}^3$ of water, which has an osmotic pressure of $0.1 \text{ atm}$ at $300 \text{ K}$. [Molar mass of solute = $328 \text{ g mol}^{-1}$, $R = 0.082 \text{ dm}^3 \text{atm K}^{-1} \text{mol}^{-1}$] (in $\text{ g}$)

Which of the following statements is correct for an aqueous solution of $6 \ g \ L^{-1}$ urea and $17.12 \ g \ L^{-1}$ sucrose? [Molar mass of urea $= 60 \ g \ mol^{-1}$,Molar mass of sucrose $= 342 \ g \ mol^{-1}$]