Which of the following liquid mixtures shows a positive deviation from Raoult's law?

Which one of the following is true for an exothermic reaction $A \rightleftharpoons B$,if $E_f$ and $E_b$ are the activation energies of forward and backward reactions respectively?

$A$ circular disc of radius $R$ is removed from a bigger circular disc of radius $2R$ such that the circumferences of the discs touch. The centre of mass of the new disc is at a distance $\alpha R$ from the centre of the bigger disc. The value of $\alpha$ is

$A$ small source of sound vibrating at a frequency $500 ~Hz$ is rotated along a circle of radius $\frac{100}{\pi} ~cm$ at a constant angular speed of $5 ~revolutions ~per ~second$. The minimum and maximum frequency of the sound observed by a listener situated in the plane of the circle is (speed of sound is $332 ~ms^{-1}$).

Western Ghats have a large number of plant and animal species that are not found anywhere else. Which of the following terms is used to denote such species?

The mean of four observations is $3$. If the sum of the squares of these observations is $48$,then their standard deviation is