Which of the following amines does not evolve $N_2$ gas upon reaction with $HNO_2$?

Give the structure of $A$ in the following reaction.
$2\text{-Nitro-4-methylaniline} \xrightarrow[(ii) \ H_3PO_2, H_2O]{(i) NaNO_2 + HCl, 273 - 278 \ K} A$.

The reduction of benzenediazonium chloride to phenylhydrazine can be accomplished by:

Isomeric amines with molecular formula $C_8H_{11}N$ give the following tests:
Isomer $(P) \Rightarrow$ Can be prepared by Gabriel phthalimide synthesis.
Isomer $(Q) \Rightarrow$ Reacts with Hinsberg's reagent to give a solid insoluble in $NaOH$.
Isomer $(R) \Rightarrow$ Reacts with $HONO$ followed by $\beta$-naphthol in $NaOH$ to give a red dye.
Isomers $(P), (Q)$ and $(R)$ respectively are:

Given below are two statements:
Statement $I$ : The $NH_2$ group in Aniline is ortho and para directing and a powerful activating group.
Statement $II$ : Aniline does not undergo Friedel-Craft's reaction (alkylation and acylation).
In the light of the above statements,choose the most appropriate answer from the options given below :

$A$ reaction of $0.1 \ mol$ of Benzylamine with bromomethane gave $23 \ g$ of Benzyl trimethyl ammonium bromide. The number of moles of bromomethane consumed in this reaction are $n \times 10^{-1},$ when $n = \dots$ (Round off to the Nearest Integer).
(Given : Atomic masses: $C : 12.0 \ u, H : 1.0 \ u, N : 14.0 \ u, Br : 80.0 \ u$)