What is obtained by the reaction of toluene with chlorine in the presence of iron and in the absence of light?

  • A
    $o$-chlorotoluene
  • B
    $p$-chlorotoluene
  • C
    Benzyl chloride
  • D
    $A$ mixture of $(o)$-chlorotoluene and $(p)$-chlorotoluene

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$C_{6}H_{6} + CH_{3}Cl \xrightarrow{\text{Anhy. } AlCl_{3}} C_{6}H_{5}CH_{3} + HCl$
The name of the above reaction is:

Arrange the following compounds in decreasing order of their reactivity towards electrophilic substitution $(S_E)$ reaction: $I$. Chlorobenzene,$II$. Benzene,$III$. Anilinium chloride,$IV$. Toluene.

Assertion : Friedel-Craft's reaction is used to introduce an alkyl or acyl group in benzene nucleus.
Reason : Benzene is a solvent for the Friedel-Craft's alkylation of bromobenzene.

Oxidation of toluene with dilute $HNO_3$ gives:

The chemicals used for preparing acetophenone via Friedel-Crafts acylation are:
$(A)$ $C_6H_6$
$(B)$ $CH_3COCH_3$
$(C)$ $CH_3COCl$
$(D)$ Anhydrous $AlCl_3$

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