Which of the following amino acids is achiral?

  • A
    $2-$Ethylalanine
  • B
    $2-$Methylglycine
  • C
    $2-$Hydroxymethylserine
  • D
    Tryptophan

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$A$ tetrapeptide has a $-COOH$ group on alanine. This produces glycine $(Gly)$,valine $(Val)$,phenylalanine $(Phe)$,and alanine $(Ala)$ on complete hydrolysis. For this tetrapeptide,the number of possible sequences (primary structures) with the $-NH_2$ group attached to a chiral center is:

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