What is the enol form of acetone after reaction with $D_2O$?

  • A
    $CH_3-C(OD)=CH_2$
  • B
    $CD_3-CO-CD_3$
  • C
    $CH_2=C(OH)-CH_2D$
  • D
    $CD_2=C(OH)-CD_3$

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$A$ reaction of benzonitrile with one equivalent of $CH_{3}MgBr$ followed by hydrolysis produces a yellow liquid $P$. The compound $P$ will give a positive result for which of the following tests?

An aldehyde or ketone containing at least one $\alpha-H$ atom reacts with dilute $NaOH$ to form a $\beta-$hydroxy aldehyde or $\beta-$hydroxy ketone. This reaction is known as $—$

Hex$-4-$en$-2-$ol on treatment with $PCC$ gives $'A'.$ $'A'$ on reaction with sodium hypoiodite gives $'B',$ which on further heating with soda lime gives $'C'.$ The compound $'C'$ is $....... .$

Match List-$I$ with List-$II$.
List-$I$ (Reactions)List-$II$ (Reagents)
$(A)$ $CH_3(CH_2)_5COOC_2H_5 \rightarrow CH_3(CH_2)_5CHO$$(I)$ $CH_3MgBr, H_2O$
$(B)$ $C_6H_5COC_6H_5 \rightarrow C_6H_5CH_2C_6H_5$$(II)$ $Zn(Hg)$ and conc. $HCl$
$(C)$ $C_6H_5CHO \rightarrow C_6H_5CH(OH)CH_3$$(III)$ $NaBH_4, H^+$
$(D)$ $CH_3COCH_2COOC_2H_5 \rightarrow CH_3CH(OH)CH_2COOC_2H_5$$(IV)$ $DIBAL-H, H_2O$

Choose the correct answer from the options given below:

The ratio $x / y$ on completion of the above reaction is $.........$.

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