The heat required to raise the temperature of $5$ moles of $O_2$ from $10\,^{\circ}C$ to $20\,^{\circ}C$ at constant volume is ....... $cal$. Given: $C_p = 7.2\,cal/mol/^{\circ}C$ and $R = 2\,cal/mol/^{\circ}C$.

  • A
    $25$
  • B
    $50$
  • C
    $250$
  • D
    $500$

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Given below are observations on molar specific heats at room temperature of some common gases.
Gas Molar specific heat $(C_v)$ $(cal\, mol^{-1}\, K^{-1})$
Hydrogen $4.87$
Nitrogen $4.97$
Oxygen $5.02$
Nitric oxide $4.99$
Carbon monoxide $5.01$
Chlorine $6.17$

The measured molar specific heats of these gases are markedly different from those for monatomic gases. Typically,molar specific heat of a monatomic gas is $2.92 \; cal/mol\; K$. Explain this difference. What can you infer from the somewhat larger (than the rest) value for chlorine?

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