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(B) $p$-Nitrophenol exhibits intermolecular hydrogen bonding,which leads to the association of molecules and higher boiling point. In contrast,$o$-nit

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Hydrogen bonding

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(B) $p$-Nitrophenol exhibits intermolecular hydrogen bonding,which leads to the association of molecules and higher boiling point. In contrast,$o$-nitrophenol exhibits intramolecular hydrogen bonding,which prevents the association of molecules. Due to the lack of intermolecular association,$o$-nitrophenol has a lower boiling point and is more volatile than $p$-nitrophenol.

Which of the following concepts best explains why $o$-nitrophenol is more volatile than $p$-nitrophenol?

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