$A$ hydrogen electrode is immersed in a solution with $pH = 0$ $(HCl)$. By how much will the potential (reduction) change if an equivalent amount of $NaOH$ is added to the solution? (Take $pH_2 = 1 \ atm$,$T = 298 \ K$).

  • A
    increase by $0.41 \ V$
  • B
    increase by $59 \ mV$
  • C
    decrease by $0.41 \ V$
  • D
    decrease by $59 \ mV$

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$A$ battery is constructed of $Cr$ and $Na_2Cr_2O_7$. The unbalanced chemical equation when such a battery discharges is: $Na_2Cr_2O_7 + Cr + H^{+} \to Cr^{3+} + H_2O + Na^{+}$. If one Faraday of electricity is passed through the battery during charging,the number of moles of $Cr^{3+}$ removed from the solution is:

On the basis of standard electrode potential values $(E^{\circ})$, suggest which of the following reactions would take place spontaneously? Given: $E^{\circ}_{Zn^{2+}/Zn} = -0.76 \ V$, $E^{\circ}_{Cu^{2+}/Cu} = +0.34 \ V$, $E^{\circ}_{Mg^{2+}/Mg} = -2.37 \ V$, $E^{\circ}_{Fe^{2+}/Fe} = -0.44 \ V$, $E^{\circ}_{Br_{2}/Br^{-}} = +1.09 \ V$, $E^{\circ}_{Cl_{2}/Cl^{-}} = +1.36 \ V$, $E^{\circ}_{Cd^{2+}/Cd} = -0.40 \ V$.

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Given below are two statements:
Statement $I$: For $KI$,molar conductivity increases steeply with dilution.
Statement $II$: For carbonic acid,molar conductivity increases slowly with dilution.
In the light of the above statements,choose the correct answer from the options given below:

If $\Lambda^{0}_{NaCl} = 126 \ S \ cm^{2} \ mol^{-1}$,$\Lambda^{0}_{KBr} = 125 \ S \ cm^{2} \ mol^{-1}$,and $\Lambda^{0}_{KCl} = 150 \ S \ cm^{2} \ mol^{-1}$,then find $\Lambda^{0}_{NaBr}$ in $S \ cm^{2} \ mol^{-1}$.

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