Among the following complexes,which one can a | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) In a redox reaction,an oxidising agent accepts electrons and undergoes reduction.For a metal carbonyl complex to act as an oxidising agent,it shou

Vedclass · Accepted Answer

$[V(CO)_6]$

Vedclass · Answer

(D) In a redox reaction,an oxidising agent accepts electrons and undergoes reduction.For a metal carbonyl complex to act as an oxidising agent,it should ideally have an $EAN$ (Effective Atomic Number) less than the atomic number of the nearest noble gas to achieve stability by gaining an electron.For $[V(CO)_6]$,the $EAN$ is calculated as: $V$ $(Z=23)$ + $6 	imes 2$ (from $CO$) = $23 + 12 = 35$.The nearest noble gas is Krypton $(Kr)$ with $Z=36$.Since $35 < 36$,the complex $[V(CO)_6]$ readily accepts an electron to form $[V(CO)_6]^-$,which has an $EAN$ of $36$,thereby acting as an oxidising agent.

Among the following complexes,which one can act as an oxidising agent?

Similar Questions

Which of the following is formed when $n$-butyl lithium reacts with tin$(II)$ chloride?

Explain homoleptic carbonyl compounds.

Which of the following is not an organometallic compound?

Which of the following compounds is not considered an organometallic compound?

The organometallic compound $(CH_3)_3 CMgBr$ on reaction with $D_2 O$ produces . . . . . . .

Vedclass Test Series

Exam Paper Generator

Online Exam Module