Among the following options,select the option in which each complex in Set-$I$ shows geometrical isomerism and the two complexes in Set-$II$ are ionization isomers of each other.
$[en = H_2N-CH_2-CH_2-NH_2]$
$[en = H_2N-CH_2-CH_2-NH_2]$
- ASet-$I$: $[Ni(CO)_4]$ and $[PdCl_2(PPh_3)_2]$
Set-$II$: $[Co(NH_3)_5Cl]SO_4$ and $[Co(NH_3)_5(SO_4)]Cl$ - BSet-$I$: $[Co(en)(NH_3)_2Cl_2]$ and $[PdCl_2(PPh_3)_2]$
Set-$II$: $[Co(NH_3)_6][Cr(CN)_6]$ and $[Cr(NH_3)_6][Co(CN)_6]$ - CSet-$I$: $[Co(NH_3)_3(NO_2)_3]$ and $[Co(en)_2Cl_2]$
Set-$II$: $[Co(NH_3)_5Cl]SO_4$ and $[Co(NH_3)_5(SO_4)]Cl$ - DSet-$I$: $[Cr(NH_3)_5Cl]Cl_2$ and $[Co(en)(NH_3)_2Cl_2]$
Set-$II$: $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$
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Similar Questions
Consider the complex ions,$trans-[Co(en)_2Cl_2]^+$ $(A)$ and $cis-[Co(en)_2Cl_2]^+$ $(B)$. The correct statement regarding them is :
Indicate the number of unpaired electrons in $K_3[Fe(CN)_6]$ and $K_4[Fe(CN)_6]$.
MediumWBJEE 2021
View SolutionThere are four complexes of $Ni$. Select the complex(es) which will be attracted by a magnetic field:
$(I) \ [Ni(CN)_4]^{2-}, \ (II) \ [NiCl_4]^{2-}, \ (III) \ [Ni(CO)_4]$
$(IV) \ [Ni(H_2O)_6]^{2+}$
$(I) \ [Ni(CN)_4]^{2-}, \ (II) \ [NiCl_4]^{2-}, \ (III) \ [Ni(CO)_4]$
$(IV) \ [Ni(H_2O)_6]^{2+}$
Select the correct code of $TRUE$ and $FALSE$ for the given statements:
$(a)$ Peroxide ion as well as dioxygen molecule both are paramagnetic species.
$(b)$ In the set of isomers,$[Cr(H_2O)_6]Cl_3$ and $[CrCl(H_2O)_5]Cl_2 \cdot H_2O$,both compounds can easily lose water molecules on treatment with conc. $H_2SO_4$.
$(c)$ During the transformation $NO \to NO^+$,bond length decreases and magnetic behavior changes from paramagnetic to diamagnetic.
$(d)$ An ether is more volatile than an alcohol,both having the same molecular formula.
$(a)$ Peroxide ion as well as dioxygen molecule both are paramagnetic species.
$(b)$ In the set of isomers,$[Cr(H_2O)_6]Cl_3$ and $[CrCl(H_2O)_5]Cl_2 \cdot H_2O$,both compounds can easily lose water molecules on treatment with conc. $H_2SO_4$.
$(c)$ During the transformation $NO \to NO^+$,bond length decreases and magnetic behavior changes from paramagnetic to diamagnetic.
$(d)$ An ether is more volatile than an alcohol,both having the same molecular formula.
Difficult
View SolutionExplain the magnetic properties of coordination compounds.
Medium
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