An exothermic reaction $X \rightarrow Y$ has an activation energy of $30 \ kJ \ mol^{-1}$. If the energy change $\Delta E$ during the reaction is $-20 \ kJ \ mol^{-1}$,then the activation energy for the reverse reaction in $kJ \ mol^{-1}$ is $...$.

  • A
    $40$
  • B
    $250$
  • C
    $50$
  • D
    $150$

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The reaction: $Cr_{2}O_{3} + 2 Al \rightarrow Al_{2}O_{3} + 2 Cr$ $\quad (\Delta_{r}G^{\Theta} = -421 \ kJ)$ is thermodynamically feasible as is apparent from the Gibbs energy value. Why does it not take place at room temperature?

The rate constants of a reaction at $500 \, K$ and $700 \, K$ are $0.02 \, s^{-1}$ and $0.07 \, s^{-1}$ respectively. Calculate the values of $E_{a}$ and $A$.

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For a reversible reaction $A \rightleftharpoons B$,which one of the following statements is wrong from the given energy profile diagram?

$A \rightarrow B$
The rate constants of the above reaction at $200 \, K$ and $300 \, K$ are $0.03 \, min^{-1}$ and $0.05 \, min^{-1}$ respectively. The activation energy for the reaction is $.... \, J$ (Nearest integer).
(Given: $\ln 10 = 2.3$,$R = 8.3 \, J \, K^{-1} \, mol^{-1}$,$\log 5 = 0.70$,$\log 3 = 0.48$,$\log 2 = 0.30$)

The temperature dependence of the rate constant $k$ is expressed as $k = A e^{-E_a / RT}$. When a plot between $\log k$ and $1/T$ is plotted,we get the graph as shown. What is the value of the slope in the graph?

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