An oxidation-reduction reaction in which $3$ electrons are transferred has a $\Delta G^{\circ}$ of $17.37 \ kJ \ mol^{-1}$ at $25^{\circ} C$. The value of $E_{\text{cell}}^{\circ}$ (in $V$) is........ $\times 10^{-2} \ V$.
$(1 \ F = 96,500 \ C \ mol^{-1})$

  • A
    $6$
  • B
    $8$
  • C
    $10$
  • D
    $12$

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Consider the cell at $25^{\circ} C$:
$Zn | Zn^{2+}_{(aq)} (1 \ M) || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
The fraction of total iron present as $Fe^{3+}$ ion at the cell potential of $1.500 \ V$ is $X \times 10^{-2}$. The value of $X$ is $.....$ (Nearest integer).
(Given $E^{0}_{Fe^{3+} / Fe^{2+}} = 0.77 \ V, E^{0}_{Zn^{2+} / Zn} = -0.76 \ V$)

For the cell reaction,$A_{(s)} + B^{2+}_{(aq)} \rightarrow A^{2+}_{(aq)} + B_{(s)}$,if the equilibrium constant of the reaction is $10^4$ at $298 \ K$,what is the standard $EMF$ of the cell (in $V$)?

Consider the following half-cell reaction: $Cr_2O_7^{2-}{_{\text{(aq)}}} + 14H^{+}{_{\text{(aq)}}} + 6e^{-} \rightarrow 2Cr^{3+}{_{\text{(aq)}}} + 7H_2O_{\text{(l)}}$. The reaction was conducted with the ratio $\frac{[Cr^{3+}]^2}{[Cr_2O_7^{2-}]} = 10^{-6}$. The $pH$ value at which the $EMF$ of the half-cell will become zero is $............$ (nearest integer value). [Given: standard half-cell reduction potential $E^{o}_{Cr_2O_7^{2-}, H^{+} / Cr^{3+}} = 1.33 \ V$,$\frac{2.303 RT}{F} = 0.059 \ V$]

The half-cell reaction involving the quinhydrone electrode is shown below:
$HO-C_6H_4-OH_{(aq)} \rightleftharpoons O=C_6H_4=O_{(aq)} + 2H^+ + 2e^-$
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If the $E^{\circ}_{cell}$ for a given reaction has a negative value,which of the following gives the correct relationships for the values of $\Delta G^{\circ}$ and $K_{eq}$ ?

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