Arrange the elements $N$,$P$,$O$,and $S$ in the order of:
$(i)$ Increasing first ionisation enthalpy.
$(ii)$ Increasing non-metallic character.
Give reasons for the arrangement assigned.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The positions of the elements in the periodic table are as follows:
Period Group $15$ and $16$
$2$nd period $N$ (Group $15$),$O$ (Group $16$)
$3$rd period $P$ (Group $15$),$S$ (Group $16$)

$(i)$ Ionisation enthalpy of nitrogen $(N: 1s^2, 2s^2, 2p^3)$ is greater than oxygen $(O: 1s^2, 2s^2, 2p^4)$ due to the extra stability of the exactly half-filled $2p$-orbitals. Similarly,the ionisation enthalpy of phosphorus $(P: 1s^2, 2s^2, 2p^6, 3s^2, 3p^3)$ is greater than sulphur $(S: 1s^2, 2s^2, 2p^6, 3s^2, 3p^4)$.
On moving down a group,ionisation enthalpy decreases due to an increase in atomic size. Therefore,the order of increasing first ionisation enthalpy is: $S < P < O < N$.
$(ii)$ Non-metallic character increases across a period (left to right) and decreases down a group. Therefore,the order of increasing non-metallic character is: $P < S < N < O$.

Explore More

Similar Questions

The number of the following pairs of elements which exhibit a diagonal relationship is:
$1. B \text{ and } Si$
$2. Be \text{ and } Al$
$3. Li \text{ and } Mg$
$4. Al \text{ and } S$

$(a)$ $Be$ and $Mg$ are alkaline earth metals.
$(b)$ $K^{+}$ has larger radii than $Ca^{2+}$.
$(c)$ All $d$-block elements are transition elements.
$(d)$ $H^{-}$ ion is larger than $F^{-}$.
Incorrect statement is/are

Which one of the following is a different pair?

Fill in the blanks given below:
$(i)$ The most widely used scale for measuring electronegativity is ........ .
$(ii)$ The similarity observed in periodic properties is known as .............. .
$(iii)$ The elements located in the middle of the periodic table form .......... type of oxides.

An element of atomic weight $40$ has $2, 8, 8, 2$ as the electronic configuration. Which one of the following statements regarding this element is not correct?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo