Assertion : According to transition state theory for the formation of an activated complex,one of the vibrational degrees of freedom is converted into a translational degree of freedom.
Reason : Energy of the activated complex is higher than the energy of reactant molecules.

  • A
    If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
  • B
    If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
  • C
    If the Assertion is correct but Reason is incorrect.
  • D
    If both the Assertion and Reason are incorrect.

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Similar Questions

The rate constant of a first order reaction is $3.46 \times 10^{-2} \ s^{-1}$ at $298 \ K$. What is the rate constant of the reaction at $350 \ K$ if its activation energy is $50.1 \ kJ \ mol^{-1}$ (in $s^{-1}$)? $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$
$(\log 2 = 0.3010)$

$A$ chemical reaction was carried out at $300 \, K$ and $280 \, K$. The rate constants were found to be $K_1$ and $K_2$ respectively. The energy of activation is $1.157 \times 10^4 \, cal \, mol^{-1}$ and $R = 1.987 \, cal \, K^{-1} \, mol^{-1}$. Then:

The temperature dependence of the rate constant $(k)$ of a chemical reaction is expressed by the Arrhenius equation,$k = A \cdot e^{-E^*/RT}$. The activation energy $(E^*)$ of the reaction can be calculated by plotting:

The variation of the rate constant with temperature is given by the Arrhenius equation $k = A e^{-E_a / (RT)}$. If $T \to \infty$,the rate constant $k$ will be equal to:

The correct reaction profile diagram for a positive catalyst reaction.

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